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Regional secondary PM Possible

2007-08-13 Knoxville, TN regional secondary-particle pollution episode

August 13, 2007

Daily PM2.5 peaked at 62.4 µg/m³ near Knoxville across 1 covered metro home to 957,608 people. 1 metro placed a top-ten day in their record.

Counting the extra PM2.5 above each metro's typical day, this event handed the average affected resident ≈ 2.3 cigarettes. Across everyone living in the affected metros, that is the collective equivalent of ≈ 2.2 million cigarettes. An awareness illustration of outdoor exposure at 22 µg/m³ per cigarette (Berkeley Earth), counting only the event's ranked days; not a medical dose.

Why we think this happened

The basis for “Regional secondary PM”

EPA's exact-date CSN sample for Knoxville, TN shows sulfate plus nitrate made up a literal majority of reconstructed PM2.5 mass. This supports regional secondary-particle pollution as a possible mechanism without naming a specific emitter.

Possible This is a transparent hypothesis supported by limited evidence or an explicit inference, not a definitive attribution.

U.S. EPA AirData Chemical Speciation Network hypothesis

Knoxville, TN PM2.5 composition on 2007-08-13

EPA's exact-date CSN sample reconstructed a median 18.8 µg/m³ of PM2.5. Ammonium sulfate and ammonium nitrate contributed a median 13.1 µg/m³, or 69.7% of reconstructed mass; every usable site exceeded 50%.

NOAA/NWS surface observations via Iowa Environmental Mesonet · Aug 13, 2007 hypothesis

KNOXVILLE MUNICIPAL haze observations during the PM2.5 event

KNOXVILLE MUNICIPAL, 31 km from the target PM2.5 monitor, reported haze during 5 observed hours. Winds were at or below 3 knots during 13 representative hours.

Inference, not direct attribution

Same-day particle composition: EPA speciation observations on the peak date show a majority secondary-inorganic aerosol signature. This supports a regional secondary-particle mechanism, not a single emitting source.

See every retained source and limitation ↓

Evidence path

From source to city

A cause is more convincing when the record connects three things: something happened, the air mass moved toward the region, and local instruments responded. Here is how much of that chain is documented for this event.

Open the evidence ledger ↓
  1. 1

    Source or mechanism

    Pattern-based explanation

    Same-day particle composition. EPA speciation observations on the peak date show a majority secondary-inorganic aerosol signature. This supports a regional secondary-particle mechanism, not a single emitting source.

    Inferred
  2. 2

    Air-mass movement

    The 72-hour air-mass history is reconstructed

    NOAA HYSPLIT modeled 12 backward paths across multiple arrival times and heights. They show where the air traveled, not which source polluted it.

    Explore the modeled paths ↓
    Modeled
  3. 3

    Local response

    62.4 µg/m³ near Knoxville

    EPA monitors recorded the event across 1 metro. The peak daily concentration is roughly 2.8 cigarette-equivalents at the outdoor daily rate.

    Inspect the pollutant and weather signals ↓
    Documented

Event autopsy

What the instruments saw

Before, during, and after the episode: nearby pollutant monitors and surface-weather stations show what changed. This context tests the “Regional secondary PM” explanation; it does not assign the cause by itself.

Observed context · not attribution

Knoxville, TN

Monitor comparison window 2007-08-10 to 2007-08-16 · PM2.5 target: Loudon Pope site

5 pollutant signals
Fine-particle pulse 29.9 µg/m³

23% above nearby days

Air movement 2 kt

About the same as surrounding days

PM10 36 µg/m³

About the same as surrounding days

Pollution fingerprint

Metro-wide median of reporting monitors
PM2.5 29.9 µg/m³

23% higher than surrounding days

Before18.1 µg/m³ Event29.9 µg/m³ After27.1 µg/m³
7 monitors · 24 HOUR
PM10 36 µg/m³

About the same as surrounding days

Before28 µg/m³ Event36 µg/m³ After35 µg/m³
1 monitor · 24-HR BLK AVG
Carbon monoxide 0.176 ppm

About the same as surrounding days

Before0.155 ppm Event0.176 ppm After0.175 ppm
1 monitor · 1 HOUR
Sulfur dioxide 2.85 ppb

8% higher than surrounding days

Before2.40 ppb Event2.85 ppb After2.63 ppb
3 monitors · 1 HOUR
Ozone 0.047 ppm

6% lower than surrounding days

Before0.048 ppm Event0.047 ppm After0.050 ppm
6 monitors · 8-HR RUN AVG BEGIN HOUR

Atmospheric conditions

Nearby EPA weather observations
Humidity 66.3 %

About the same as surrounding days

Temperature 76.4 °F

About the same as surrounding days

Wind 2 kt

About the same as surrounding days

Source: U.S. EPA AirData daily observations and, where available, nearby ASOS/AWOS surface observations. Values are descriptive medians over the retained monitor set; missing measurements remain missing. Transport and source evidence remain separate layers because this instrument pattern does not assign a cause by itself.

Air-mass reconstruction

Where the air had been

NOAA HYSPLIT traces the air arriving at each metro backward for 72 hours. Multiple arrival times and heights show whether the broad path is stable—or sensitive to assumptions about when and where the polluted layer arrived.

Transport context · not source attribution

Air arriving near Knoxville

Peak-date arrivals · 2007-08-13

Broad history Mostly north of the metro
72-hour reach 400–1,200 km
Sensitivity runs 12 modeled paths
Arrival metro
Near surface · 100 mLower atmosphere · 500 mHigher layer · 1,000 m

Each line begins 72 hours before arrival and points toward the metro. Color represents arrival height; repeated lines represent 00, 06, 12, and 18 UTC arrival assumptions. A path can show where the air traveled, but it cannot prove which source added the PM2.5.

Measured daily PM2.5 at EPA monitors, as cigarette-equivalents
EPA monitors sit in metro areas, so the colour clusters there. Land between and beyond them is unmeasured, not clean: this map shows where IAQng has readings, not the extent of the smoke.

Episode peak

-- cigarettes

The smoke map's scale, replayed over this event: the surface interpolates between covered metros' daily records, framed to the affected region. Hover for a reading, click a metro to pin it to the card. Days a monitor did not report draw nothing.

Views from the selected metro

Camera views near

Browse the camera map →

Select a metro on the map to see nearby cameras. Where an operator archive reaches the event, drag the divider to compare two moments, adjust either date and time, or play the available event-day frames. Camera imagery is visual context, not an air-quality measurement or proof of smoke.

Affected metros

MetroPeak PM2.5Cigarettes, whole eventPeak dayAll-time standing
Knoxville, TN 62.4 µg/m³ 2.8 Aug 13, 2007 #9 of its top days

"Cigarettes, whole event" totals a metro's ranked event days at 22 µg/m³ per cigarette: what a person outdoors there breathed across the event, as the illustration. "All-time standing" is where this episode's days sit in each metro's ranked record (worst-area measure, since 1999). Full local context is on each metro's Air Records page.

Public evidence library

What supports this account

Each card states what a source supports—and what it does not. Official records, research, reporting, community observations, and transparent inferences remain visibly different kinds of evidence.

4 retained sources

Official record

KNOXVILLE MUNICIPAL haze observations during the PM2.5 event

NOAA/NWS surface observations via Iowa Environmental Mesonet

KNOXVILLE MUNICIPAL, 31 km from the target PM2.5 monitor, reported haze during 5 observed hours. Winds were at or below 3 knots during 13 representative hours.

What it supports

This source supports a possible mechanism or occurrence; it does not establish the cause by itself.

Limit

The airport and regulatory pollution monitors are nearby but not co-located.

Official record

Knoxville, TN PM2.5 composition on 2007-08-13

U.S. EPA AirData Chemical Speciation Network

EPA's exact-date CSN sample reconstructed a median 18.8 µg/m³ of PM2.5. Ammonium sulfate and ammonium nitrate contributed a median 13.1 µg/m³, or 69.7% of reconstructed mass; every usable site exceeded 50%.

What it supports

This source supports a possible mechanism or occurrence; it does not establish the cause by itself.

Limit

Chemical composition identifies the measured aerosol mechanism, not a particular emitting facility or upwind source region.

Measured data

Peak-date reconstructed aerosol composition

U.S. EPA Chemical Speciation Network

On the affected place peak date, reconstructed ammonium sulfate plus ammonium nitrate represented a majority of EPA reconstructed mass at every usable sampled site. knoxville: median 70% (minimum 70% across 1 site).

What it supports

Measured composition consistent with secondary-inorganic-dominated PM2.5 at sampled monitors on the local peak date.

Limit

A component majority describes aerosol composition at sampled monitors; it does not identify an emitting source.

Transparent inference

Secondary-inorganic component majority

IAQng deterministic inference policy

Under csn_secondary_inorganic_majority_on_peak_date.v1, complete affected-place peak-date coverage with a secondary-inorganic majority creates a possible regional-secondary-PM hypothesis.

What it supports

A possible regional secondary PM hypothesis; this is a reproducible inference, not direct source attribution.

Limit

A component majority describes aerosol composition at sampled monitors; it does not identify an emitting source.

What remains uncertain

Status and provenance

Possible This is a transparent hypothesis supported by limited evidence or an explicit inference, not a definitive attribution.

This episode was grouped from the monitor record by the catalog pipeline and given its cause from the evidence listed above. It has not been individually reviewed and signed off, so its boundaries, cause, and name may change as evidence accumulates. Grouping policy common_sense_root_cause_grouping.v2. The cause label reflects the assembled evidence above, not an IAQng detection formula. If it is wrong, tell us.